Autor: |
Meulemans, Tommi M., Stork, Gerrit A., Jansen, Ben J.M., de Groot, Aede |
Zdroj: |
Tetrahedron Letters; January 1998, Vol. 39 Issue: 36 p6565-6568, 4p |
Abstrakt: |
Copper ( I) catalysed conjugate addition of methylmagnesium iodide to R-(−)-carvone and trapping the enolate as its trimethylsilyl enol ether, followed by a trityl perchlorate (TrClO 4) catalysed Mukaiyama-aldol reaction, is an efficient method for the preparation of highly functionalised cyclohexanones which can be used as starting compounds in the total syntheses of enantiomerically pure clerodanes. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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