| Autor: |
Bodwell, Graham J., Houghton, Tom J., Miller, David |
| Zdroj: |
Tetrahedron Letters; January 1997, Vol. 38 Issue: 9 p1469-1472, 4p |
| Abstrakt: |
The title compound was synthesized by a two-fold BOP-Cl mediated esterification of o-phenylenediacetic acid with catechol. The presence of the bridging esters results in a considerable change in the conformational landscape of the cyclophane system in comparison to the parent [3.3]orthocyclophane and related systems. A conformer search at the AM1 level identified six low energy conformers. The one observed in the solid state was calculated to be the second lowest in energy, 0.32 kcal/mol above the calculated global minimum. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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