An unusual alkylation with trifluoroiodomethane providing a difluoroiodomethyl group
| Autor: | Letourneau, Johnathon E, Burnell, D.Jean |
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| Zdroj: | Tetrahedron Letters; January 1997, Vol. 38 Issue: 8 p1353-1354, 2p |
| Abstrakt: | Pentamethylcyclopentadienyllithium reacted with trifluoroiodomethane to provide a diene bearing a difluoroiodomethyl group and none of the trifluoromethyl diene. This result was consistent with insertion of difluorocarbene into the C-1 bond of an initially formed iodo-diene. |
| Databáze: | Supplemental Index |
| Externí odkaz: |
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