Asymmetric allylic alkylation catalyzed by palladium complexes with a new chiral bisphosphine ligand
Autor: | Longmire, James M., Zhu, Guoxin, Zhang, Xumu |
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Zdroj: | Tetrahedron Letters; January 1997, Vol. 38 Issue: 3 p375-378, 4p |
Abstrakt: | A novel, chiral bisphosphine ligand has been synthesized and its palladium complexes have been used in asymmetric allylic alkylation. High reactivity and moderate selectivity have been realized in the reaction between 1,3-diphenyl-2-propenyl acetate and dimethyl malonate. |
Databáze: | Supplemental Index |
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