Asymmetric allylic alkylation catalyzed by palladium complexes with a new chiral bisphosphine ligand

Autor: Longmire, James M., Zhu, Guoxin, Zhang, Xumu
Zdroj: Tetrahedron Letters; January 1997, Vol. 38 Issue: 3 p375-378, 4p
Abstrakt: A novel, chiral bisphosphine ligand has been synthesized and its palladium complexes have been used in asymmetric allylic alkylation. High reactivity and moderate selectivity have been realized in the reaction between 1,3-diphenyl-2-propenyl acetate and dimethyl malonate.
Databáze: Supplemental Index