The role of alkoxyl radicals in Gif (GoAgg V) chemistry

Autor: Snelgrove, Darren W., MacFaul, Philip A., Keith U., Ingold, Wayner, Danial D.M.
Zdroj: Tetrahedron Letters; January 1996, Vol. 37 Issue: 6 p823-826, 4p
Abstrakt: The oxidation of cyclooctane using tert-alkyl hydroperoxides under GoAgg Vconditions has been examined using selected alkyl hydroperoxides as mechanistic probes. The results indicate that the products are formed by alkoxyl radical-induced reactions, there being no need to invoke any chemistry involving high valent iron-oxo species.
Databáze: Supplemental Index