Separation, by G.L.C., of enantiomeric sugars as diastereoisomeric dithioacetals

Autor: Little, Mark R.
Zdroj: Carbohydrate Research; July 1982, Vol. 105 Issue: 1 p1-8, 8p
Abstrakt: The reaction between (+)-1-phenylethanethiol and each of a pair of enantiomeric sugars produced two acyclic, diastereoisomeric dithioacetals. These diastereomers were then separated by gas-liquid chromatography. This method was applied to separate the following pairs of enantiomers: d- and l-arabinose, d- and l-lyxose, d- and l-fucose, d- and l-rhamnose, d- and l-galactose, d- and l-glucose, and d- and l-mannose.
Databáze: Supplemental Index