Halogen-induced selectivity in heterogeneous epoxidation is an electronic effectfluorine, chlorine, bromine and iodine in the Ag-catalysed selective oxidation of ethene
Autor: | Lambert, Richard M., Cropley, Rachael L., Husain, Alifiya, Tikhov, Mintcho S. |
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Zdroj: | Chemical Communications; 2003, Vol. 2003 Issue: 10 p1184-1185, 2p |
Abstrakt: | Selectivity promotion in the Ag-catalysed heterogeneous epoxidation of ethene correlates with halogen electron affinity showing that it is an electronic phenomenon rather than a steric or geometrical effect. |
Databáze: | Supplemental Index |
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