Halogen-induced selectivity in heterogeneous epoxidation is an electronic effect—fluorine, chlorine, bromine and iodine in the Ag-catalysed selective oxidation of ethene

Autor: Lambert, Richard M., Cropley, Rachael L., Husain, Alifiya, Tikhov, Mintcho S.
Zdroj: Chemical Communications; 2003, Vol. 2003 Issue: 10 p1184-1185, 2p
Abstrakt: Selectivity promotion in the Ag-catalysed heterogeneous epoxidation of ethene correlates with halogen electron affinity showing that it is an electronic phenomenon rather than a steric or geometrical effect.
Databáze: Supplemental Index