| Autor: |
Pham, Phuc H., Doan, Son H., Tran, Hang T. T., Nguyen, Ngoc N., Phan, Anh N. Q., Le, Ha V., Tu, Thach N., Phan, Nam T. S. |
| Zdroj: |
Catalysis Science & Technology; 2018, Vol. 8 Issue: 5 p1267-1271, 5p |
| Abstrakt: |
A new mixed-linker iron-based MOF VNU-20 [Fe3(BTC)(NDC)2·6.65H2O] was solvothermally synthesized from 1,3,5-benzenetricarboxylic acid, 2,6-naphthalenedicarboxylic acid and FeCl2. VNU-20 was utilized as a recyclable catalyst for the functionalization of coumarins with N,N-dimethylanilines viadirect C–H bond activation. This Fe-MOF was found to be more active towards the coupling transformation than several conventional homogeneous and MOF-based heterogeneous catalysts. To the best of our knowledge, this is the first time that [Fe3(CO2)7]∞SBUs are evaluated for their catalytic activity, and this transformation of coumarins is new. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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