| Autor: |
Zhang, Ye-Zheng, Zhang, Ze, Liu, Sheng, Li, Guo-Ran, Gao, Xue-Ping |
| Zdroj: |
ACS Applied Materials & Interfaces; February 2018, Vol. 10 Issue: 10 p8749-8757, 9p |
| Abstrakt: |
Low sulfur utilization and poor cycle life of the sulfur cathode with high sulfur loadings remain a great challenge for lithium–sulfur (Li–S) battery. Herein, the free-standing carbon film consisting of porous carbon nanofibers (PCNFs) and carbon nanotubes (CNTs) is successfully fabricated by the electrospinning technology. The PCNF/CNT film with three-dimensional and interconnected structure is promising for the uniformity of the high-loading sulfur, good penetration of the electrolyte, and reliable accommodation of volumetric expansion of the sulfur cathode. In addition, the abundant N/O-doped elements in PCNF/CNT film are helpful to chemically trap soluble polysulfides in the charge–discharge processes. Consequently, the obtained monolayer S/PCNF/CNT film as the cathode shows high specific capacity, excellent cycle stability, and rate stability with the sulfur loading of 3.9 mg cm–2. Moreover, the high areal capacity of 13.5 mA h cm–2is obtained for the cathode by stacking three S/PCNF/CNT layers with the high sulfur loading of 12 mg cm–2. The stacking-layered cathode with high sulfur loading provides excellent cycle stability, which is beneficial to fabricate high-energy-density Li–S battery in future. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
