| Autor: |
Zhao, Xianhui, Walker, Devin M., Maiti, Debtanu, Petrov, Amanda D., Kastelic, Matthew, Joseph, Babu, Kuhn, John N. |
| Zdroj: |
Industrial & Engineering Chemistry Research; 20240101, Issue: Preprints |
| Abstrakt: |
Cylindrical NiMg/Ce0.6Zr0.4O2pellet catalysts with two different sizes (large, radius = 1.59 mm; small, radius = 0.75 mm) were produced by extrusion of powder catalysts. The small catalyst pellets had a higher specific surface area, pore volume, average pore size, radial crush strength, and resistance to breakage than the large pellets. Tri-reforming tests with surrogate biogas were conducted at 3 bar and 882 °C, with the feed molar ratios of CH4:CO2:air fixed at 1.0:0.7:0.95 and the H2O/CH4molar feed ratio varied (0.35–1.16). The small catalyst pellets exhibited lower internal mass-transfer resistance and higher coking resistance compared to the large pellets. CO2conversion decreased and H2/CO molar ratio increased with the increase of H2O/CH4molar feed ratio, which are consistent with the trends predicted by thermodynamic equilibrium calculations. The results indicate that the NiMg/Ce0.6Zr0.4O2catalyst pellets are promising for commercial scale applications. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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