| Autor: |
Kostina, S. A., Bryukov, M. G., Shestov, A. A., Knyazev, V. D. |
| Zdroj: |
The Journal of Physical Chemistry - Part A; March 2003, Vol. 107 Issue: 11 p1776-1778, 3p |
| Abstrakt: |
The reaction C2Cl3 + Cl2 → C2Cl4 + Cl has been studied using the laser photolysis/photoionization mass spectrometry technique. Rate constants were determined in time-resolved experiments as a function of temperature (299−668 K). Rate constants of the above reaction are independent of the bath gas density within the experimental range, [He] = (3−12) × 1016 atom cm-3. Within the above experimental range of temperatures, the rate constants of the above reaction can be described by the modified Arrhenius expression k1 = 3.79 × 10-15 T0.87 exp(−55 K/T) cm3 molecule-1 s-1. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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