| Autor: |
Taç, Doğan, Aytaç, İsmet Arınç, Karatavuk, Ali Osman, Kuş, Melih, Ziyanak, Fırat, Artok, Levent |
| Zdroj: |
Asian Journal of Organic Chemistry; October 2017, Vol. 6 Issue: 10 p1330-1330, 1p |
| Abstrakt: |
Iron Age: Iron‐promoted reactions of enyne oxiranes or acetate derivatives of 2‐en‐4‐yne alcohols with Grignard reagents produce (E)‐configured vinylallenes. The reaction cycle involves two successively formed organoiron intermediates: first, a π‐allyl iron intermediate forms. Then, the subsequent shift of the iron unit to the distal alkynyl carbon leads to a lower energy intermediate, σ‐allenyl iron complex. More information can be found in the Full Paper by Levent Artok et al. on page 1415 in Issue 10, 2017(DOI: 10.1002/ajoc.201700225). |
| Databáze: |
Supplemental Index |
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