| Autor: |
Werz, D. B., Gleiter, R., Rominger, F. |
| Zdroj: |
Organometallics; February 2003, Vol. 22 Issue: 4 p843-849, 7p |
| Abstrakt: |
The synthesis of bis(methyltelluro)alkynes with two (2), three (3), and four (4) alkyne units was achieved. The key step was the reaction of the corresponding bis(trimethylsilyl)alkynes 10−12 with methyllithium, tellurium, and methyliodide in a one-pot reaction. The structures of 2−4 as well as that of bis(methyltelluro)acetylene (1) were investigated in the solid state. All four samples showed C2 symmetry in the solid state. For 1−4 we found relatively short Te···Te contacts of two neighbors, giving rise to a zigzag arrangement between the Te centers and forming stacks of molecules. The He(I) and He(II) photoelectron spectra of 1 as well as the UV/vis spectra of 1−4 are reported and discussed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
