| Autor: |
Wu, Meng-Meng, Wang, Jiao-Yang, Sun, Rui, Zhao, Cui, Zhao, Jiong-Peng, Che, Guang-Bo, Liu, Fu-Chen |
| Zdroj: |
Inorganic Chemistry; 20240101, Issue: Preprints |
| Abstrakt: |
Introducing another chromophore into a luminescent MOF is a potential way to assembling novel dual-emissive luminescent materials. Putting the chromophore, for which luminescence can be enhanced by Zn2+ion, into MOF-5 by the “bottle around ship” strategy is a simple but efficient synthesis method to realize such dual-emissive materials. According to this strategy, a novel dual-emissive luminescent composite material [Zn2(HL)3]+@MOF-5 was constructed by loading the [La3(HL)2L2(NO3)3H2O] (1) (H2L = 7,7′-(ethane-1,1′-diyl)8-hydro-quinoline) into MOF-5, in which the [Zn2(HL)3]+anions were transformed from 1with the existence of Zn2+. The dual-emissive composite materials show excellent luminescence with two emissions of MOF-5 at 410 nm and [Zn2(HL)3]+at 524 nm. Furthermore, by combining characteristics of MOF-5 and the guest chromophore, the composite material is highly selectively sensitive toward Al3+and monoethanolamine, which makes [Zn2(HL)3]+@MOF-5 a potential self-calibrated fluorescence sensor. |
| Databáze: |
Supplemental Index |
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