| Autor: |
Girnus, Irina, Hoffmann, Katrin, Marlow, Frank, Caro, Jürgen, Döring, Günter |
| Zdroj: |
Microporous Materials; July 1994, Vol. 2 Issue: 6 p537-541, 5p |
| Abstrakt: |
Large CoAPO-5 crystals were synthesized by microwave heating of a fluoride-containing aluminophosphate gel. By polarization microscopy and polarization-dependent single-crystal ultraviolet—visible (UV—VIS) spectroscopy, the as-synthesized crystals show an optical anisotropy of light absorption. It is proposed that this effect originates from structure-related symmetry distortions of the tetrahedral Co2+environment in the AFI framework. Consequently, the effect of anisotropic optical absorption can be taken as a proof for the incorporation of cobalt in the AFI framework. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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