Predicting the Claisen rearrangement regioselectivity of allylindanyl and allyltetrahydronaphthalenyl ether derivatives by 1H NMR experiments

Autor: Rodrigues, Denise C., Fernandes, Sergio A., Marsaioli, Anita J.
Zdroj: Magnetic Resonance in Chemistry; November 2000, Vol. 38 Issue: 11 p970-974, 5p
Abstrakt: The regioselectivity of the Claisen rearrangement of allylindanyl and allyltetrahydronaphthalenyl ether derivatives can be predicted by conformational preference detected by 1H NMR NOE difference spectra and T1 measurements. Copyright © 2000 John Wiley & Sons, Ltd.
Databáze: Supplemental Index