Synthesis of Long-Chain Fatty Acid Enol Esters Isolated from an Environmental DNA Clone

Autor:	Brady, S. F., Clardy, J.
Zdroj:	Organic Letters; January 2003, Vol. 5 Issue: 2 p121-124, 4p
Abstrakt:	Long-chain fatty acid enol ester 1 is the major metabolite of a new family of small molecules isolated from the heterologous expression of environmentally derived DNA. A versatile synthesis of 1, in which an aromatic acetaldehyde is O-acylated with a long-chain acyl chloride allowed for the rapid construction of both the isolated product (1) and a number of structural analogues (including 8, 17, and 18).
Databáze:	Supplemental Index
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