Microstructure Similarities between Phases F and U in Al-Pd-Co Alloys

Autor: Černičková, Ivona, Adamech, Marek, Ďuriška, Libor, Drienovský, Marian, Janičkovič, Dusan, Priputen, Pavol, Janovec, Jozef
Zdroj: Diffusion and Defect Data Part B: Solid State Phenomena; December 2016, Vol. 258 Issue: 1 p440-443, 4p
Abstrakt: The work is aimed at searching for compositionally variant isostructural mutations of the cubic F-phase in both as-annealed (850°C/500 h) and DTA-cooled conditions of the Al72Pd9Co19 alloy. Recently, the mutations were reported for the U-phase in the Al69.8Pd13.8Co16.4 alloy annealed at 700°C for 2000 h. In the investigation, scanning electron microscopy including energy dispersive X-ray spectroscopy, powder X-ray diffraction, and differential thermal analysis (DTA) were used. Two isostructural mutations of the F-phase, FL (the product of L-parent) and FV (the product of V-parent), were identified (symbol L stands for liquid). On DTA-cooling, the bivariant heterogeneous transition (Lpart→V), the monovariant heterogeneous transformation (Lrest→V+FL), and the monovariant quasi-eutectoid transformation (Vrest→Al5Co2+FV) were recorded.
Databáze: Supplemental Index