Determination of the Acidity of Long Chain Alcohols Using Infrared Multiple Photon Dissociation

Autor: Wong, J., Walthall, D. A., Brauman, J. I.
Zdroj: The Journal of Physical Chemistry - Part A; December 2002, Vol. 106 Issue: 51 p12299-12304, 6p
Abstrakt: The acidities of the long chain normal alcohols, 1-pentanol to 1-nonanol, were determined using infrared multiple photon activation of alcohol−alkoxide complexes in an ion cyclotron resonance mass spectrometer. We evaluate the applicability of infrared multiple photon dissociation (IRMPD) as a kinetic method for thermochemical determinations by comparing our results to previous studies using different experimental methods.
Databáze: Supplemental Index