Large-Scale Production of V6O13Cathode Materials Assisted by Thermal Gravimetric Analysis–Infrared Spectroscopy Technology

Autor: Liang, Han-Pu, Du, Jian, Jones, Timothy G. J., Lawrence, Nathan S., Meredith, Andrew W.
Zdroj: ACS Applied Materials & Interfaces; October 2016, Vol. 8 Issue: 39 p25674-25679, 6p
Abstrakt: The kilogram-scale fabrication of V6O13cathode materials has been notably assisted by in situ thermal gravimetric analysis (TGA)–infrared spectroscopy (IR) technology. This technology successfully identified a residue of ammonium metavanadate in commercial V6O13, which is consistent with the X-ray photoelectron spectroscopy result. Samples of V6O13materials have been fabricated and characterized by TGA–IR, scanning electron microscopy, and X-ray diffraction. The initial testing results at 125 °C have shown that test cells containing the sample prepared at 500 °C show up to a 10% increase in the initial specific capacity in comparison with commercial V6O13.
Databáze: Supplemental Index