Free Radical-Mediated Vinyl Amination:  Access to N,N-Dialkyl Enamines and Their β-Stannyl and β-Thio Derivatives

Autor: Prabhakaran, E. N., Nugent, B. M., Williams, A. L., Nailor, K. E., Johnston, J. N.
Zdroj: Organic Letters; November 2002, Vol. 4 Issue: 24 p4197-4200, 4p
Abstrakt: The first examples of free radical-mediated vinyl amination are described by nonconventional vinyl radical addition to azomethine nitrogen. This new vinyl amination protocol is mild and provides convenient synthetic access to nonstabilized N,N-dialkyl enamines and tandem bond-forming processes.
Databáze: Supplemental Index