Reaction of Acyl Chlorides with In Situ Formed Zinc Selenolates: Synthesis of Selenoesters versus Ring-Opening Reaction of Tetrahydrofuran

Autor: Bellino, Gemma, Scisciani, Marialaura, Pinto Vargas, Jaqueline, Sancineto, Luca, Bagnoli, Luana, Marini, Francesca, Seibert Lüdtke, Diogo, Joao Lenardao, Eder, Santi, Claudio
Zdroj: Journal of Chemistry; 2016, Vol. 2016 Issue: 1
Abstrakt: Attempting to apply the in situ production of PhSeZnSePh to the synthesis of selenoesters, an unexpected reaction involving the solvent (tetrahydrofuran) was observed and studied. We reported here some evidences about the mechanism and the possibility to control the chemoselectivity of this new reaction that afforded the formation of interesting selenoderivatives in which the selenium moiety and the carboxylic one are spaced by four carbon units.
Databáze: Supplemental Index