ChemInform Abstract: Cyclometalation of 2,6‐Di‐tert‐butylphenoxide Ligands by Tantalum Aryl Groups: Aliphatic Carbon‐Hydrogen Bond Activation and Aryl Isomerization via Benzyne (o‐Phenylene) Intermediates.
Autor: | CHAMBERLAIN, L. R., KERSCHNER, J. L., ROTHWELL, A. P., ROTHWELL, I. P., HUFFMAN, J. C. |
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Zdroj: | ChemInform; February 1988, Vol. 19 Issue: 6 pno-no |
Abstrakt: | Alkylation of the halides (I) with 3 equiv. phenyllithium (II) leads to the monocyclometalated compounds (III) directly along with the formation of benzene. |
Databáze: | Supplemental Index |
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