ChemInform Abstract: Cyclometalation of 2,6‐Di‐tert‐butylphenoxide Ligands by Tantalum Aryl Groups: Aliphatic Carbon‐Hydrogen Bond Activation and Aryl Isomerization via Benzyne (o‐Phenylene) Intermediates.

Autor: CHAMBERLAIN, L. R., KERSCHNER, J. L., ROTHWELL, A. P., ROTHWELL, I. P., HUFFMAN, J. C.
Zdroj: ChemInform; February 1988, Vol. 19 Issue: 6 pno-no
Abstrakt: Alkylation of the halides (I) with 3 equiv. phenyllithium (II) leads to the monocyclometalated compounds (III) directly along with the formation of benzene.
Databáze: Supplemental Index