| Autor: |
Katagiri, Toshimasa, Yamaji, Sachiko, Handa, Michiharu, Irie, Minoru, Uneyama, Kenji |
| Zdroj: |
Chemical Communications; October 15, 2001, Vol. 2001 Issue: 20 p2054-2055, 2p |
| Abstrakt: |
Intramolecular electrostatic repulsions between the local negative charge on a trifluoromethyl group and that on the ortho position of an aryl moiety of a nucleophile was found to be a controlling factor of the diastereoselectivity in a cyclopropanation reaction, in which the electrostatic repulsion was evaluated quantitatively. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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