Symmetry of quantum intramolecular dynamics

Autor: Burenin, Alexander V.
Zdroj: Physics-Uspekhi; October 2, 2002, Vol. 45 Issue: 7 p753-776, 24p
Abstrakt: The paper reviews the current progress in describing quantum intramolecular dynamics using merely symmetry principles as a basis. This closed qualitative approach is of particular interest because it is the only method currently available for a broad class of topical problems in the internal dynamics of molecules. Moreover, a molecule makes a physical system whose collective internal motions are geometrically structured, so that its description by perturbation methods requires a symmetry analysis of this structure. The nature of the geometrical symmetry groups crucial for the closed formulation of the qualitative approach is discussed. In particular, the point group of a molecule is of this type.
Databáze: Supplemental Index