N-substituted phenothiazines as redox indicators in titrations with chloramine-T and chloramine-B

Autor: Gowda, H.Sanke, Mohan, B.M., Ahmed, S.Akheel
Zdroj: Talanta; December 1980, Vol. 27 Issue: 12 p1084-1086, 3p
Abstrakt: Profenamine hydrochloride, fluphenazine dihydrochloride, trifluopromazine hydrochloride, cyamepromazine maleate, perphenazine dihydrochloride and mepazine hydrochloride are proposed as redox indicators in the titration of hydroquinone, metol and ascorbic acid with chloramine-T and chloramine-B in sulphuric, hydrochloric and acetic acid media. They give a sharp reversible colour change at the equivalence point. A simple but accurate method for the determination of hydroquinone, metol and ascorbic acid is described. The conditional potentials and molar absorptivities of the indicators and redox potential of chloramine-B are reported.
Databáze: Supplemental Index