Formation of 4-arylpyridines from pyridinium salts under the action of methylammonium sulfite
Autor: | Gromov, S., Kurchavov, N. |
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Zdroj: | Russian Chemical Bulletin; July 2003, Vol. 52 Issue: 7 p1606-1609, 4p |
Abstrakt: | Reactions of pyridinium salts or nonquaternized pyridine with 4-methylpyridinium salts in the presence of methylammonium sulfite in aqueous methylamine afford 4-phenylpyridine in 29—57% yields. The probable mechanism of ring transformation in simplest pyridine derivatives under the action of nucleophiles is discussed. |
Databáze: | Supplemental Index |
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