Formation of 4-arylpyridines from pyridinium salts under the action of methylammonium sulfite

Autor: Gromov, S., Kurchavov, N.
Zdroj: Russian Chemical Bulletin; July 2003, Vol. 52 Issue: 7 p1606-1609, 4p
Abstrakt: Reactions of pyridinium salts or nonquaternized pyridine with 4-methylpyridinium salts in the presence of methylammonium sulfite in aqueous methylamine afford 4-phenylpyridine in 29—57% yields. The probable mechanism of ring transformation in simplest pyridine derivatives under the action of nucleophiles is discussed.
Databáze: Supplemental Index