Electrocatalytic transformation of malononitrile and cycloalkylidenemalononitriles into spirotricyclic and spirotetracyclic compounds containing cyclopropane and pyrroline fragments

Autor: Elinson, M., Fedukovich, S., Zaimovskaya, T., Vereshchagin, A., Nikishin, G.
Zdroj: Russian Chemical Bulletin; October 2003, Vol. 52 Issue: 10 p2241-2246, 6p
Abstrakt: Electrolysis of cycloalkylidenemalononitriles and malononitrile in MeOH in an undivided cell in the presence of the NaBr—NaOMe mediator system gives spirotricyclic compounds containing cyclopropane and pyrroline fragments in 50—77% yields. Spirobicyclic and spirotricyclic tetracyanocyclopropanes undergo electrolysis in alcohols to afford spirotricyclic and spirotetracyclic products containing cyclopropane and pyrroline fragments in 50—93% yields.
Databáze: Supplemental Index
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