Kinetics and Mechanism of Oxidative Dehydrodisproportionation of Methylcyclohexane on Modified High-Silica Zeolite H-TsVM

Autor: Alimardanov, Kh., Velieva, F., Tairova, L.
Zdroj: Russian Journal of Applied Chemistry; August 2002, Vol. 75 Issue: 8 p1256-1261, 6p
Abstrakt: The kinetics of oxidative dehydrodisproportionation of methylcyclohexane in the presence of H-TsVM zeolite (SiO2: Al2O3= 30) modified with gallium and gadolinium oxides was studied. A kinetic model fairly adequately describing this process in a wide temperature range was proposed. The kinetic constants of some oxidation reactions were determined.
Databáze: Supplemental Index