| Autor: |
Shvo, Youval, Czarkie, Dorotha |
| Zdroj: |
Journal of Organometallic Chemistry; November 1986, Vol. 315 Issue: 1 pC25-C28, 4p |
| Abstrakt: |
With water tricarbonyl-tetrahapto-tetraphenylcyclopentadienoneruthenium(O) (1) undergoes a water-gas type reaction whereby a coordinated CO is oxidized to CO2, and gives the dimeric complex, which was isolated in high yield. A catalytic reduction of ketones with CO and water under mild conditions has been developed, and a catalytic cycle proposed. A turnover frequency of 1.2 min−1, which is increased by a factor of ca. 6 by the presence of sodium carbonate, has been observed in the reactions with cyclohexanone. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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