Synthesis of High-Molecular Weight Poly(vinyl alcohol) of Various Tactic Contents through Photo-Emulsion Copolymerization of Vinyl Acetate and Vinyl Pivalate

Autor: Yamamoto, Tohei, Fukae, Ryohei, Saso, Tomoaki, Sangen, Osamu, Kamachi, Mikiharu, Sato, Toshiaki, Fukunishi, Yoshiharu
Zdroj: Polymer Journal; January 1992, Vol. 24 Issue: 1 p115-119, 5p
Abstrakt: Photo-emulsion copolymerizations of vinyl acetate (VAc) and vinyl pivalate (VP) were carried out without initiator at 0°C, and copolymers giving high molecular weight poly(vinyl alcohol) (PVA) with various tacticities were obtained. The tacticities could be controlled between 22.3–12.8% for the isotactic triad and 27.7–38.3% for the syndiotactic triad by varying feed monomer composition.
Databáze: Supplemental Index