Calix[4]arene-Functionalized Naphthalene and Perylene Imide Dyes

Autor: Vysotsky, M. O., Bohmer, V., Wurthner, F., You, C.-C., Rissanen, K.
Zdroj: Organic Letters; August 2002, Vol. 4 Issue: 17 p2901-2904, 4p
Abstrakt: Calix[4]arenes bearing one, two, or four 1,8-naphthyl imide groups at the wide rim and bis-calix[4]arenes connected via perylene-bisimide dye spacers have been synthesized. The low-temperature NMR spectrum of the tetranaphthylimide suggests, in agreement with a crystal structure, a C2-symmetrical pinched cone conformation stabilized via face-to-face π−π interactions between opposite naphthylimide groups. UV−vis and fluorescence studies have been carried out for the perylene bis-calix[4]arene dyes.
Databáze: Supplemental Index