Synthesis and structural characterization of a silver complex of a mixed-donor N-heterocyclic carbene linked cyclophaneElectronic supplementary information (ESI) available: detailed experimental procedures for the syntheses of [1][PF6]2 and [Ag4(1*)2][PF6]4 (2) and details of crystallography. See http://www.rsc.org/suppdata/cc/b1/b105751k

Autor: Garrison, Jered C., Simons, Richard S., Kofron, William G., Tessier, Claire A., Youngs, Wiley J.
Zdroj: Chemical Communications; September 14, 2001, Vol. 2001 Issue: 18 p1780-1781, 2p
Abstrakt: The synthesis of a dicationic imidazolium-linked cyclophane and a dimeric silver–N-heterocyclic carbene complex, that is the first silver complex with a N-heterocyclic carbene ligand involved in a π-bonding interaction, is reported.
Databáze: Supplemental Index