The oxidation induced rearrangement of carbapenems to carbacephams

Autor: Feigelson, Gregg B.
Zdroj: Tetrahedron Letters; May 1998, Vol. 39 Issue: 21 p3387-3390, 4p
Abstrakt: Upon dihydroxylation, carbapenems with an exocyclic vinyl sulfone at C-2 were found to rearrange to 2-keto-3-hydroxy carbacephams. These products could then be converted into the corresponding carbacephems.
Databáze: Supplemental Index