N-Trimethylgermyl-triorganophosphinimine / N-Trimethylgermyl Triorganophosphine Imines

Autor: Wolfsberger, Werner
Zdroj: Zeitschrift für Naturforschung B; February 1977, Vol. 32 Issue: 2 p152-156, 5p
Abstrakt: A series of N-trimethylgermyl triorganophosphine imines have been prepared by three different routes, (1) from tertiary phosphines and trimethylgermyl azide, (2) from triorganophosphine imines and trimethylgermyl chloride and (3) by methylation of N-trichlorogermyl phosphine imines. With one exception all phosphine imines react with trimethylaluminium to yield 1/1-adducts. The new compounds were characterized by elemental analyses, molecular weight determinations, IR and 1H and 31P NMR spectra.
Databáze: Supplemental Index