NOTIZEN: Bildung und Reaktion Si-fluorierter 1.3.5-Trisila-cyclohexane / Formation and Reactions of Si-fluorinated 1,3,5-Trisilacyclohexanes

Autor: Fritz, G., Portner, M.
Zdroj: Zeitschrift für Naturforschung B; December 1975, Vol. 30 p965-968, 4p
Abstrakt: The reaction of 1,3,5-Trisilacyclohexanes containing Si—F and C—Cl groups and CH3MgCl starts with methylation of the Si—F group (in contrast to the reactions of the corresponding Si—Cl containing derivatives). At a certain degree of methylation a ring contraction starts at the C—Cl group.
Databáze: Supplemental Index