| Autor: |
Buchner, Wolfgang, Wolfsberger, Werner |
| Zdroj: |
Zeitschrift für Naturforschung B; June 1974, Vol. 29 Issue: 5-6 p328-334, 7p |
| Abstrakt: |
Phosphorus-31 and carbon-13 chemical shifts as well as 31P - 13C and 31P - 29Si coupling constants have been obtained from a series of ten N -trim ethylsilyl-triorganophosphine imines. The influence of alkyl substituents on the phosphorus-31 chemical shifts in these and a variety of other com pounds is explained by a mechanism of intram olecular coordination of the β-CH3group to phosphorus using d-orbitals. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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