A New Phosphorylation Method via O-Diethylboryl Intermediates

Autor: Dahlhoff, Wilhelm V., Taba, Kalulu M.
Zdroj: Zeitschrift für Naturforschung B; October 1989, Vol. 44 Issue: 10 p1260-1262, 3p
Abstrakt: Diphenylchlorophosphine and diethylchlorophosphite react with acetylacetone to generate intermediate phosphine enolates 3 which are quenched with O-diethylboryl derivatives and then oxidized with hydrogen peroxide to give diphenylphosphinates 4 and diethylphosphates 5.
Databáze: Supplemental Index