| Autor: |
Ellermann, Jochen, Lindner, Helmut A., Schössner, Horst, Thiele, Gerhard, Zoubek, Gerd |
| Zdroj: |
Zeitschrift für Naturforschung B; December 1978, Vol. 33 Issue: 12 p1386-1392, 7p |
| Abstrakt: |
The organocyclotriarsane, CH3C(CH2As)3(1), reacts with chromium hexacarbonyl on ultraviolet irradiation to give the complex CH3C(CH2As)3Cr(CO)5(2), in which the cyclo-triarsane is behaving as a monodentate ligand. The crystal structure of 2 has been determinated by X-ray diffraction. The monoclinic unit cell (space group P21/n) contains 4 isolated molecules in a hexagonal closest packing. The mass spectrum of 2 shows the parent peak and clear fragmentation patterns. The infrared and Raman spectra are reported for 1 and 2 in the 3000-30 cm-1region. Most of the fundamental vibrations are assigned. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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