Chemie polyfunktioneller Liganden, 56 [1]. Darstellung von N-Deutero-bis(diphenylphosphino)amin, sowie schwingungsspektroskopischer Vergleich mit Bis(diphenylphosphino)amin und Lithium-bis(diphenylphosphino)amid / Chemistry of Polyfunctional Ligands, 56 [1]. Preparation of N-Deutero-bis(diphenylphosphino)amine, as well as the Vibrational Spectroscopic Comparison with Bis(diphenylphosphino)amine and Lithium-bis(diphenylphosphino)amid

Autor: Eilermann, Jochen, Lietz, Martin
Zdroj: Zeitschrift für Naturforschung B; January 1980, Vol. 35 Issue: 1 p64-67, 4p
Abstrakt: Bis(diphenylphosphino)amine, [(C6H5)P2NH (1), can be metallated with n-butyl-lithium to hthium-bis(diphenylphosphino)amid, [(C6H5)P2NLi (2), It reacts with CH3OD to give N-Deutero-bis(diphenylphosphino)amine, [(C6H5)P2ND (3). The compounds were characterized by infrared, Raman, 1H and 31P NMR spectroscopy.
Databáze: Supplemental Index