| Abstrakt: |
Phenazine free E2P-TCNQ, C28H22N6, Mr= 442.53 is monoclinic, P21/c, a = 10.875(3), b = 14.679(4), c = 14.526(2) Å, β = 90.90(2)°, V = 2321.9 Å3, Z = 4, dc= 1.27 Mgm-3, the compound doped with 50% phenazine, E2P-P-(TCNQ)2C52H34N12, Mr= 826.93, is triclinic, P1̅, a = 7.739(3), b = 15.899(6), c = 17.037(7) Å, α = 83.44(3), β = 88.34(3), γ = 83.19(3)°, V = 2067.7 Å, Z = 2, dc= 1.33 Mgm-3. E2P-TCNQ was refined to R = 0.066 for 1880 reflections. It consists of planar TCNQ anions and bent E2P cations (dihedral angle 17.7° along the line N-N) arranged in regular mixed stacks along c. The structure of E2P-P-(TCNQ)2could be solved principally, but did not refine well (R = 0.165 for 1206 reflections). Regular segregated stacks of the phenazine and the TCNQ moieties are formed, and along the cationic stack the E2P+cations and the neutral phenazine molecules alternate. |
