Tunable Diode Laser Spectra and Assignment of the 748 cm-1Band of Propane

Autor: Gassler, G., Reißenauer, B., Hüttner, W.
Zdroj: Zeitschrift für Naturforschung A; April 1989, Vol. 44 Issue: 4 p316-324, 9p
Abstrakt: The rotational structure of the 748 cm-1c-type CH2-rocking fundamental of propane was analysed using tunable diode laser (TDL) techniques. On grounds of a low-resolution Fourier transform (FTIR) spectrum and of the known ground-state rotational and centrifugal-distortion constants, some 700 transitions were measured and assigned in several regions of the band. The upper-state constants determined in this way allow the prediction of rovibrational frequencies to within 0.003 cm-1, covering quantum states up to J = 50 and Ka= 20. The band appears unperturbed.
Databáze: Supplemental Index