Reactions of Dicyanogen and Cyanogen Halides with the Biscyclopentadienyls of Vanadium and Chromium

Autor: Morán, Moisés, Gayoso, Miguel
Zdroj: Zeitschrift für Naturforschung B; February 1983, Vol. 38 Issue: 2 p177-180, 4p
Abstrakt: The oxidative addition of dicyanogen, (CN)2, and of the cyanogen halides, XCN (X = Cl, Br or I), to the biscyclopentadienyl compounds of vanadium and chromium, (η-C5H5)2M (M = V or Cr), leads to the formation of (η-C5H5)2MX(CN) (X = CN, Cl, Br, I; M = V or Cr). The synthesized compounds have been characterized by elemental analyses, IR and EPR spectra, and determinations of the magnetic moments.
Databáze: Supplemental Index