Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines

Autor: Dick, Stefan, Weiss, Armin, Wagner, Ursel, Wagner, Friedrich, Große, Gerhard
Zdroj: Zeitschrift für Naturforschung B; March 1997, Vol. 52 Issue: 3 p372-384, 13p
Abstrakt: Tridentate amines of the type N-alkyl-N,N -bis(2-pyridylmethyl)amine with alkyl = methyl L1, benzyl L2 and adamantyl L3 form mononuclear Fe(III) complexes LFeCl3. In the presence of various carboxylates binuclear μ-oxo-bis(μ-carboxylato) Fe(III) complexes [L2Fe2O(RCO2)2]2+are formed. These compounds can be synthesized from mono-, bi-, tri- and tetranuclear iron complexes as starting materials.
Databáze: Supplemental Index