| Autor: |
Jaseer, E. A., Akhtar, Muhammad N., Osman, Mogahid, Al-Shammari, A., Oladipo, Habeebllah B., Garcés, Karin, Fernández-Alvarez, Francisco J., Al-Khattaf, Sulaiman, Oro, Luis A. |
| Zdroj: |
Catalysis Science & Technology; 2014, Vol. 5 Issue: 1 p274-279, 6p |
| Abstrakt: |
The iridium(iii) complex [Ir(H)(CF3SO3)(NSiN)(coe)] (NSiN = bis(pyridine-2-yloxy)methylsilyl, coe = cyclooctene) has been demonstrated to be an active catalyst for the solvent-free hydrosilylation of CO2with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HMTS) under mild reaction conditions (3 bar). The activity of this catalytic system depends on the reaction temperature. The best catalytic performance has been achieved at 75 °C. A kinetic study at variable temperature (from 25 °C to 75 °C) and constant pressure (3 bar) together with kinetic modeling has been carried out. The results from such a study show an activation energy of 73.8 kJ mol−1for the process. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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