| Autor: |
YOSHII, Hidefumi, FURUTA, Takeshi, ITOH, Takatoki, MISAWA, Yoshihisa, HATA, Noriaki, KOBAYASHI, Hideaki, LINKO, Yu-Yen, LINKO, Pekka |
| Zdroj: |
Bioscience, Biotechnology, and Biochemistry; January 1999, Vol. 63 Issue: 8 p1336-1339, 4p |
| Abstrakt: |
On the basis of an autocatalytic and a first order reaction kinetics, a nonisothermal oxidation reaction model was developed for n-3 polyunsaturated fatty acid (PUFA) under temperature-programmed linear heating conditions. With this model, the activation energy of oxidative reaction can easily be obtained with at least three linear heating conditions. The temperature-programmed oxidation experiments of ethyl eicosapentaenoate and ethyl docosahexaenoate were done under linear heating conditions of 4 to 12 K/h. The activation energies and the frequency factors obtained were in good agreement with those by the isothermal oxidation experiments reported previously. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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