Redox-active polymer-nanoparticle hybrid materials

Autor: Watson, Keith J., Zhu, Jin, Nguyen, SonBinh T., Mirkin, Chad A.
Zdroj: Pure & Applied Chemistry; January 2000, Vol. 72 Issue: 1-2 p67-72, 6p
Abstrakt: Ring-opening metathesis polymerization was used to modify organic soluble gold nanoparticles with redox-active polymers. A gel-permeation chromatography study revealed that each nanoparticle is modified with approximately 11 polymer chains. Electrochemical studies of nanoparticles modified with block copolymers of two different redox-active groups revealed that each monomer is electrochemically accessible, while no current rectification was observed.
Databáze: Supplemental Index