NiO/Ce1−xNixO2−δas an alternative to noble metal catalysts for CO oxidationElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cy20641b

Autor: Mahammadunnisa, Sk., Manoj Kumar Reddy, P., Lingaiah, N., Subrahmanyam, Ch.
Zdroj: Catalysis Science & Technology; 2013, Vol. 3 Issue: 3 p730-736, 7p
Abstrakt: A series of NiO/CeO2catalysts were prepared by using the combustion method and characterized by using XRD, N2-physisorption, TEM, UV-visible, Raman, XPS, ICP-OES and H2-TPR. Typical results indicated the NiO/CeO2had a better performance than CeO2for CO oxidation and 15 wt% NiO/CeO2is active and stable, whereas catalysts with a higher NiO content of 20 and 30 wt% deactivated at 130 °C onwards. The high activity and excellent stability of 15% NiO/CeO2catalysts can be ascribed to their high oxygen vacancy, high dispersion of NiO and strong metal–support interaction that leads to synergy between NiO and CeO2.
Databáze: Supplemental Index