| Autor: |
Belova, Natalya V., Girichev, Georgiy V., Hinchley, Sarah L., Kuzmina, Natalya P., Rankin, David W. H., Zaitzeva, Irina G. |
| Zdroj: |
Dalton Transactions; 2004, Vol. 2004 Issue: 11 p1715-1718, 4p |
| Abstrakt: |
Combined gas electron diffractionmass spectrometry GEDMS was used to determine the molecular structure of trisdipivaloylmethanatolutetiumiii, Ludpm3dpm 2,2,6,6-tetramethyl-heptane-3,5-dionato. Up to about 520–570 K the vapour consisted only of molecules Ludpm3. The experimental data recorded at 4085 K indicate that the molecules have D3symmetry. The bond distances rh1 in the chelate ring are Lu–O 2.1976 , C–O 1.2704 and C–C 1.3906 . Theoretical computations at the HF and DFT levels with basis sets up to 6-311G afford structures similar to those found experimentally, with a distorted LuO6antiprism. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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