Spontaneous chiral resolution of a coordination polymer with distorted helical structure consisting of achiral building blocksDedicated to Professor Peter Jutzi on the occasion of his 65thbirthday.

Autor: Siemeling, Ulrich, Scheppelmann, Imke, Neumann, Beate, Stammler, Anja, Stammler, Hans-Georg, Frelek, Jadwiga
Zdroj: Chemical Communications; 2003, Vol. 2003 Issue: 17 p2236-2237, 2p
Abstrakt: Reaction of achiral 2,5-diphenyl-3,4-di3-pyridylcyclopenta-2,4-dien-1-one 2 with ZnCl2and HgBr2, respectively, afforded the helically chiral coordination polymers 2ZnCl2∞and 2HgBr2∞, which show spontaneous chiral resolution, forming colonies of homochiral crystals.
Databáze: Supplemental Index